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題名 Size effects on mixed valence CePd3
作者 陳洋元
Lin,Y. H. ;Wang,C. R. ;Dong,C. L. ;Ou,M. N. ;Chen,Y. Y.
貢獻者 應物所
日期 2011
上傳時間 29-九月-2014 15:07:37 (UTC+8)
摘要 To study the size effects on mixed-valence state of CePd3, nanoparticles of CePd3, sizes ranging from 5.2 to 9.5 nm, were prepared. The mixed valence increased from 3.3 to 3.5 as particle size reduced from bulk to 5.2 nm. This consequence was illustrated by the enhancements of valence fluctuations and 4f electron hybridization with conduction band through size reduction. Another interesting finding in the nanoparticles is that a certain fraction ~ 25% of the sample becomes trivalent which is evident from the increase of magnetic susceptibility at low temperatures.
關聯 Journal of Physics:Conference Series,273,012041
資料類型 article
DOI http://dx.doi.org/10.1088/1742-6596/273/1/012041
dc.contributor 應物所en_US
dc.creator (作者) 陳洋元zh_TW
dc.creator (作者) Lin,Y. H. ;Wang,C. R. ;Dong,C. L. ;Ou,M. N. ;Chen,Y. Y.en_US
dc.date (日期) 2011en_US
dc.date.accessioned 29-九月-2014 15:07:37 (UTC+8)-
dc.date.available 29-九月-2014 15:07:37 (UTC+8)-
dc.date.issued (上傳時間) 29-九月-2014 15:07:37 (UTC+8)-
dc.identifier.uri (URI) http://nccur.lib.nccu.edu.tw/handle/140.119/70181-
dc.description.abstract (摘要) To study the size effects on mixed-valence state of CePd3, nanoparticles of CePd3, sizes ranging from 5.2 to 9.5 nm, were prepared. The mixed valence increased from 3.3 to 3.5 as particle size reduced from bulk to 5.2 nm. This consequence was illustrated by the enhancements of valence fluctuations and 4f electron hybridization with conduction band through size reduction. Another interesting finding in the nanoparticles is that a certain fraction ~ 25% of the sample becomes trivalent which is evident from the increase of magnetic susceptibility at low temperatures.en_US
dc.format.extent 841850 bytes-
dc.format.mimetype application/pdf-
dc.language.iso en_US-
dc.relation (關聯) Journal of Physics:Conference Series,273,012041en_US
dc.title (題名) Size effects on mixed valence CePd3en_US
dc.type (資料類型) articleen
dc.identifier.doi (DOI) 10.1088/1742-6596/273/1/012041-
dc.doi.uri (DOI) http://dx.doi.org/10.1088/1742-6596/273/1/012041-