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題名 Gapless band structure of PbPdO2: A combined first principles calculation and experimental study
作者 郭光宇
Chen, S. W. ; Huang, S. C. ; Guo, G. Y. ; Lee, . M. ; Chiang, S. ; Chen, W. C. ; Liang, Y. C. ; Lu, K. T. ; Chen, J. M.
貢獻者 應物所
日期 2011.07
上傳時間 28-Apr-2014 17:42:23 (UTC+8)
摘要 We present experimental evidence of the gapless band structure of PbPdO2 by combined x-ray photoemission and x-ray absorption spectra complemented with first principles band structure calculations. The electronic structure near the Fermi level of PbPdO2 is mainly composed of O 2p and Pd 4d bands, constructing the conduction path along the Pd-O layer in PbPdO2. Pd deficiency in PbPdO2 causes decreased O 2p-Pd 4d and increased O 2p-Pb 6p hybridizations, thereby inducing a small band gap and hence reducing conductivity. Hall measurements indicate that PbPdO2 is a p-type gapless semiconductor with intrinsic hole carriers transporting in the Pd-O layers.
關聯 Applied Physics Letters, 99, 012103
資料類型 article
DOI http://dx.doi.org/10.1063/1.3607293
dc.contributor 應物所en_US
dc.creator (作者) 郭光宇zh_TW
dc.creator (作者) Chen, S. W. ; Huang, S. C. ; Guo, G. Y. ; Lee, . M. ; Chiang, S. ; Chen, W. C. ; Liang, Y. C. ; Lu, K. T. ; Chen, J. M.en_US
dc.date (日期) 2011.07en_US
dc.date.accessioned 28-Apr-2014 17:42:23 (UTC+8)-
dc.date.available 28-Apr-2014 17:42:23 (UTC+8)-
dc.date.issued (上傳時間) 28-Apr-2014 17:42:23 (UTC+8)-
dc.identifier.uri (URI) http://nccur.lib.nccu.edu.tw/handle/140.119/65646-
dc.description.abstract (摘要) We present experimental evidence of the gapless band structure of PbPdO2 by combined x-ray photoemission and x-ray absorption spectra complemented with first principles band structure calculations. The electronic structure near the Fermi level of PbPdO2 is mainly composed of O 2p and Pd 4d bands, constructing the conduction path along the Pd-O layer in PbPdO2. Pd deficiency in PbPdO2 causes decreased O 2p-Pd 4d and increased O 2p-Pb 6p hybridizations, thereby inducing a small band gap and hence reducing conductivity. Hall measurements indicate that PbPdO2 is a p-type gapless semiconductor with intrinsic hole carriers transporting in the Pd-O layers.en_US
dc.format.extent 711174 bytes-
dc.format.mimetype application/pdf-
dc.language.iso en_US-
dc.relation (關聯) Applied Physics Letters, 99, 012103en_US
dc.title (題名) Gapless band structure of PbPdO2: A combined first principles calculation and experimental studyen_US
dc.type (資料類型) articleen
dc.identifier.doi (DOI) 10.1063/1.3607293en_US
dc.doi.uri (DOI) http://dx.doi.org/10.1063/1.3607293en_US